The usage of TiO2@Fe3O4 nanocomposites synthesized by a novel and facile method as adsorbents in the separation/ preconcentration of silver ions from domestic wastewater samples

Abstract

Global population growth has led to an increase in the consumption of silver, which has a wide range of applications. This situation has increased demand for determining trace levels of silver to protect public health and the environ ment. In this study, an efcient magnetic-dispersive solid phase extraction (MDSPE) method was developed utilizing TiO2@Fe3O4 nanocomposites (NCs) as adsorbent for the separation and preconcentration of silver ions. TiO2 nano particles (NPs) were synthesized by a microwave-assisted hydrothermal method under diferent precursor solution and temperature program conditions. The procedure yielding TiO2 NPs with the homogeneous size distribution was established, and the NPs obtained with this procedure were used to modify the Fe3O4 surface. TiO2@Fe3O4 NCs and TiO2 NPs synthesized via alternative innovative methods to traditional techniques were examined by various characterization methods. Flame atomic absorption spectrometry (FAAS) was used for detection and quantifcation of analyte. All parameters expected to afect the adsorption and desorption of silver ions on the TiO2@Fe3O4 NCs were optimized. In the developed procedure, the optimum parameters were 20 mg TiO2@Fe3O4 NC, 1.5 mL potas sium hydrogen phthalate bufer solution (pH 6.0), orbital agitation for 30 min, and 0.10 mL HNO3 (2.0 M). The pro posed novel TiO2@Fe3O4-MDSPE-FAAS method exhibits detection and quantifcation limits of 0.005 and 0.017 mg kg−1 in a wide linear working range for silver ions. The method’s relevance and accuracy were evaluated by recovery experiments conducted on both actual and synthetic residential wastewater samples, yielding satisfactory percent recovery results using a matrix-matching calibration strategy.